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Di-chlorido-diphenyl-bis-(thio-urea-κS)tin(IV).

Authors
  • Sow, Yaya
  • Diop, Libasse
  • Molloy, Kieran C
  • Kociok-Köhn, Gabriele
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jan 01, 2013
Volume
69
Issue
Pt 10
Identifiers
DOI: 10.1107/S1600536813024343
PMID: 24098172
Source
Medline
License
Unknown

Abstract

The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the mol-ecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The Sn(IV) atom is coordinated by two phenyl groups, two Cl atoms and two thio-urea ligands in an all trans octa-hedral C2Cl2S2 environment. Individual mol-ecules are connected through N-H⋯Cl hydrogen bonds, leading to a three-dimensional network structure. Intra-molecular N-H⋯Cl hydrogen bonds are also present.

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