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Synthesis of a tantalum complex containing a side-bonded diphenyldiphosphene

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
364
Identifiers
DOI: 10.1016/0022-328x(89)85352-5

Abstract

Abstract The trihydrides Cp 2MH 3 (M = Nb, Ta) react with PPh 2H. The niobium derivative gives the expected monohydruro complex Cp 2Nb(H)PPh 2H, whereas Cp 2TaH 3, gives the side-on diphenyl diphosphene Cp 2Ta(H)(PPh) 2.

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