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Development of Pd/C-catalyzed cyanation of aryl halides.

Authors
  • Yu, Hannah
  • Richey, Rachel N
  • Miller, William D
  • Xu, Jiansheng
  • May, Scott A
Type
Published Article
Journal
The Journal of Organic Chemistry
Publisher
American Chemical Society
Publication Date
Jan 21, 2011
Volume
76
Issue
2
Pages
665–668
Identifiers
DOI: 10.1021/jo102037y
PMID: 21190390
Source
Medline
License
Unknown

Abstract

A practical method for palladium-catalyzed cyanation of aryl halides using Pd/C is described. The new method can be applied to a variety of aryl bromide and active aryl chloride substrates to effect efficient conversions. The process features many advantages over existing cyanation conditions and the practical utility of the process has been demonstrated on scale.

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