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Determination of the anomeric configuration in carbohydrates by longitudinal cross-correlated relaxation studies: application to mono- and disaccharides.

Authors
  • Pichumani, Kumar
  • Zou, Xiang
  • Chandra, Tilak
  • Brown, Kenneth L
Type
Published Article
Journal
Magnetic resonance in chemistry : MRC
Publication Date
Sep 01, 2007
Volume
45
Issue
9
Pages
734–738
Identifiers
PMID: 17640033
Source
Medline
License
Unknown

Abstract

The role of cross-correlated relaxation between the anomeric proton chemical shift anisotropy (CSA) and its dipolar relaxation with nearby proton on the longitudinal relaxation in mono- and disaccharides at two magnetic field strengths has been investigated and shown to directly report the identity of their anomeric configuration.

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