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A decatungstate-type polyoxoniobate with centered manganese: [H2Mn(IV)Nb10O32]8- as a soluble tetramethylammonium salt.

Authors
  • Son, Jung-Ho
  • Casey, William H
Type
Published Article
Journal
Dalton Transactions
Publisher
The Royal Society of Chemistry
Publication Date
Oct 07, 2013
Volume
42
Issue
37
Pages
13339–13342
Identifiers
DOI: 10.1039/c3dt51798e
PMID: 23942463
Source
Medline
License
Unknown

Abstract

A highly symmetric Mn(IV)-centered polyoxoniobate [H2Mn(IV)Nb10O32](8-) was synthesized via hydrothermal methods as a soluble tetramethylammonium salt. The structure is similar to decatungstate structure [W10O32](4-), except for the central heteroatom. The cluster is stable between 4 < pH < 10, as was characterized with ESI-MS and UV-Vis spectroscopy.

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