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The luminescence in reactions of metastable Ca and Sr atoms: Ca*+ HCl, Sr*+ Cl2under higher resolution

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
73
Issue
3
Identifiers
DOI: 10.1016/0009-2614(80)80711-1

Abstract

Abstract A new study of the luminescence emitted in the reactions Ca (4s3d 1D 2) +HCl → CaCl(A, B) +H and Sr (5s4d 1D 2, 5s5p 3P) + Cl 2 → SrCl (A,B) + Cl has been performed under higher resolution. The investigation was performed comparatively, under bimolecular-encounter and colusion-relaxed conditions. We show the utility of this procedure for molecular spectroscopy and reaction kinetics.

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