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Solvation in hydroorganic media—I. Gibbs free energy of transfer for RbCl from cationic glass electrode measurements

Authors
Journal
Electrochimica Acta
0013-4686
Publisher
Elsevier
Publication Date
Volume
21
Issue
6
Identifiers
DOI: 10.1016/0013-4686(76)85119-5

Abstract

Abstract A previously derived method for the determination of Gibbs free energies of transfer for the alkali metal chlorides using cationic glass electrodes is applied to the transfer of RbCl. Gibbs free energies for the transfer of RbCl from water to a number of water-organic solvent mixtures are reported and discussed in terms of solvation. The interest and validity of the proposed method is demonstrated.

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