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SmI2-mediated sequential radical cyclization/anionic capture of aryl iodides on solid support

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
39
Issue
16
Identifiers
DOI: 10.1016/s0040-4039(98)00292-5

Abstract

Abstract Aryl radicals were generated by SmI 2 on solid support, cyclized on to CC bond, and reduced to their organosamarium anionic species followed by electrophilic capture. However, the capture reaction was substrate-dependant in solution and on solid support. In some examples, results from solid phase reactions were equal or better to the corresponding solution reactions.

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