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Design of Velocity Map Imaging Spectrometer Equipped with a Mass Gate Discriminating Particular Photofragments

ISRN Physical Chemistry
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A photoionization spectrometer for velocity map imaging has been developed for measuring the scattering distribution of fragment ions from polyatomic molecules. The spectrometer contains a mass gate and an ion reflector which are able to discriminate ions with a particular mass-to-charge ratio m/z. The basic functions and feasibility of these devices were tested experimentally and theoretically. First, the photoions from Kr and C60 were extracted into a time-of-flight (TOF) mass spectrometer by a transient or continuous electrostatic field. When the pulse application on the mass gate was tuned to the arrival timing of ions with a specific m/z, the peak of the selected ions alone was present on a TOF spectrum. Second, compatibility between velocity map imaging and ion discrimination was investigated by the computer simulations of the ion trajectories of photofragments from C60. A pulsed voltage was applied to the mass gate synchronously with the arrival timing of C + 5 8 ions. The initial three-dimensional velocity distribution of C + 5 8 was projected onto the image plane with an energy resolution better than 10 meV. The C + 5 8 image was free from the contamination of other ions such as C + 6 0 and C + 5 6 .

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