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Small Boron Carbon Chains Stabilized in Rare Earth Metallic Frameworks: A Bonding Analysis

Authors
Journal
Journal of Solid State Chemistry
0022-4596
Publisher
Elsevier
Publication Date
Volume
133
Issue
1
Identifiers
DOI: 10.1006/jssc.1997.7425

Abstract

Abstract The bonding properties of rare earth metal boron carbide compounds are analyzed by means of extended Hückel tight-binding and ab initiocalculations. Results indicate that these compounds can be described in first approximation as being built of cumulene-like B x C y anionic units interacting with not fully oxidized metallic cations.

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