Affordable Access

Publisher Website

Epoxidation of allyl and homoallyl trimethylsilyl ethers with t-butyldioxytrimethylsilane and silicon lewis acid/vanadium catalyst

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
24
Issue
4
Identifiers
DOI: 10.1016/s0040-4039(00)81417-3

Abstract

Abstract Trimethylsilyl ethers of allyl and homoallyl alcohols are epoxidized with t-butyldoxytrimethylsilane and a catalyst system consisting of vanadyl acetoacetate and tris(trimethylsilyl)phosphate. Stereoselectivities of the oxidation are compared with the epoxidation of allyl alcohols with t-BuOOH/V catalyst and with m-chloroperbenzoic acid.

There are no comments yet on this publication. Be the first to share your thoughts.