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Di-μ-sulfato-κ4 O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline)manganese(II)] dihydrate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
66
Issue
9
Identifiers
DOI: 10.1107/s1600536810031909
Keywords
  • Metal-Organic Papers

Abstract

In the title centrosymmetric dinuclear compound, [Mn2(SO4)2(C13H8N4)2(H2O)4]·2H2O, the MnII atom is octa­hedrally coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (ip) ligand, two O atoms belonging to two bridging sulfate anions and two water O atoms. In the crystal structure, the complex mol­ecules and the uncoodinated water mol­ecules are connected by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. A π–π stacking inter­action between the pyridyl ring of the ip ligand and the benzene ring of the neighboring ligand [centroid–centroid distance = 3.579 (2) Å] is also observed.

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