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Enantioselective Bronsted acid catalyzed addition reactions of methyleneaminopyrrolidine to imines

Authors
Journal
Synlett
0936-5214
Publisher
Thieme Publishing Group
Publication Date
Issue
17
Identifiers
DOI: 10.1055/s-2005-917098
Keywords
  • Organocatalysis
  • Hydrogen Bond Donor
  • Imines
  • Hydrazone
  • Asymmetric Synthesis

Abstract

A new series of BINOL-derived multidentate Brønsted acid catalysts has been developed for the enantioselective addition of the d -synthon, methyleneaminopyrrolidine, to N-Boc imines, yielding the versatile, protected α-aminohydrazone intermediates in moderate to good ee. © Georg Thieme Verlag Stuttgart.

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