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A study of the phosphorescent triplet state of cycloalkanones by pulse optically detected magnetic resonance

Authors
Journal
Journal of Photochemistry
0047-2670
Publisher
Elsevier
Publication Date
Volume
23
Issue
3
Identifiers
DOI: 10.1016/0047-2670(83)87006-3
Disciplines
  • Chemistry

Abstract

Abstract Previous studies of saturated cycloalkanones have characterized the phosphorescent triplet state as n,π *. To elucidate further the characteristics of the excited state of these compounds of photochemical importance, we report the dephasing studies on the spin coherence in the phosphorescent triplet state. For these molecules where the excitation is localized on the carbonyl moiety, spin relaxation is a direct function of the perturbing atoms in the vicinity of the chromophore.

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