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Determination of complex association constants from gas chromatographic data:II. Complexes of silver ions with substituted alkenes in ethylene glycol at 40°C

Authors
Journal
Journal of Chromatography A
0021-9673
Publisher
Elsevier
Publication Date
Volume
76
Issue
1
Identifiers
DOI: 10.1016/s0021-9673(01)97782-9

Abstract

Abstract Association constants of substituted alkenes with silver ions in ethylene glycol have been determined by means of a previously proposed gas chromatographic method. The results have been interpreted in terms of the electronic and steric effects of the substituents and have given some indication of the type of bonding in these complexes. Some data are given on the salting out of organic compounds by electrolyte solutions in ethylene glycol.

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