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Two novel heterotrimetallic clusters of a Ag–Pt–Ag array bearing N-heterocyclic carbene: synthesis and characterization

Authors
Journal
Inorganic Chemistry Communications
1387-7003
Publisher
Elsevier
Volume
47
Identifiers
DOI: 10.1016/j.inoche.2014.07.004
Keywords
  • N-Heterocyclic Carbene
  • Platinum
  • Silver
  • Heterotrimetallic Cluster

Abstract

Abstract Two novel heterotrimetallic clusters of a linear Ag–Pt–Ag array [PtAg2(L1)](PF6)4 (1, L1=bis(N-2-pyrimidylimidazolylidenyl)methane) and [PtAg2(L2)](PF6)4 (2, L2=bis(N-pyridylimidazoliumyl)methane) were prepared and characterized by NMR, elemental analyses and X-ray single crystal diffraction analysis.

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