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Stabilization of platinum(II) hydrides by tri-t-butylarsine; facile syntheses of stabletrans-PtH2[As(t-Bu)3]2andtrans-PtHX[As(t-Bu)3]2complexes

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
186
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)82428-6

Abstract

Abstract trans-PtH 2[As(t-Bu) 3] 2 was prepared in very good yield by afacile reaction of K 2PtC1 4 with As(t-Bu) 3 in alkaline ethanol. Treatment of trans-PtH 2[As(t-Bu) 3] 2 with CF 3CO 2H or HCI afforded trans-PtH(O 2CCF 3)[As(t-Bu) 3] 2 or trans-PtHCl[As(t-Bu) 3] 2. respectively, in almost quantitative yield.

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