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Identification of the adsorbate during methanol oxidation

Authors
Journal
Journal of Electroanalytical Chemistry
0022-0728
Publisher
Elsevier
Publication Date
Volume
229
Identifiers
DOI: 10.1016/0022-0728(87)85153-7

Abstract

Abstract The formation and oxidation of the methanol adsorbate at platinum in acid solutions is performed under potential control using a flow cell technique. The charges in both processes are equal; this fact confirms the results of Podlovchenko et al. obtained from charging curves after open circuit adsorption. It is shown, using the on-line MS technique and labelled methanol, CD 3OH, that the adsorbed intermediate is probably COH.

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