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(5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ2 N,N′)cobalt(II) trihydrate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
66
Issue
11
Identifiers
DOI: 10.1107/s1600536810040560
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

The CoII atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)3]·3H2O, is six-coordinated in a CoN3O3 octa­hedral geometry; the water-coordinated CoII atom is chelated by the N-heterocycle. An inter­molecular N—H⋯O hydrogen bond occurs. The carboxyl­ate entity coordinates through the amino group. The carboxyl­ate donor unit, coordinated and uncoordinated water mol­ecules inter­act through O—H⋯O and N—H⋯O hydrogen bonds, generating a tightly-held three-dimensional cage-like network.

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