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Crystal structure of ethyl (2S)-9-meth-oxy-2-methyl-4-oxo-3,4,5,6-tetra-hydro-2H- 2,6-methano-benzo[g][1,3,5]oxa-diazocine-11-carboxyl-ate.

Authors
  • Dhandapani, A
  • Manivarman, S
  • Subashchandrabose, S
  • Gunasekaran, B
Type
Published Article
Journal
Acta Crystallographica Section E Crystallographic Communications
Publisher
International Union of Crystallography
Publication Date
Feb 01, 2015
Volume
71
Issue
Pt 2
Identifiers
DOI: 10.1107/S2056989015000559
PMID: 25878860
Source
Medline
Keywords
License
Unknown

Abstract

In the title compound, C15H18N2O5, the meth-oxy-phenyl ring makes a dihedral angle of 84.70 (12)° with the mean plane of the tetra-hydro-pyrimidin-2(1H)-one ring. Both the pyran and tetra-hydro-pyrimidin-2(1H)-one rings have distorted envelope conformations with the carboxyl-ate-substituted C atom as the flap. In the crystal, mol-ecules are linked via pairs of N-H⋯O hydrogen bonds, forming zigzag chains propagating along [010], which enclose R (2) 2(8) ring motifs. The chains are linked by C-H⋯π inter-actions, forming a two-dimensional network parallel to (100).

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