Affordable Access

deepdyve-link deepdyve-link
Publisher Website

Cross-coupling hydrogen evolution reaction in homogeneous solution without noble metals.

Authors
  • Zhong, Jian-Ji
  • Meng, Qing-Yuan
  • Liu, Bin
  • Li, Xu-Bing
  • Gao, Xue-Wang
  • Lei, Tao
  • Wu, Cheng-Juan
  • Li, Zhi-Jun
  • Tung, Chen-Ho
  • Wu, Li-Zhu
Type
Published Article
Journal
Organic Letters
Publisher
American Chemical Society
Publication Date
Apr 04, 2014
Volume
16
Issue
7
Pages
1988–1991
Identifiers
DOI: 10.1021/ol500534w
PMID: 24628016
Source
Medline
License
Unknown

Abstract

A highly efficient noble-metal-free homogeneous system for a cross-coupling hydrogen evolution (CCHE) reaction is developed. With cheap, earth-abundant eosin Y and molecular catalyst Co(dmgH)2Cl2, good to excellent yields for coupling reactions with a variety of isoquinolines and indole substrates and H2 have been achieved without any sacrificial oxidants. Mechanistic insights provide rich information on the effective, clean, and economic CCHE reaction.

Report this publication

Statistics

Seen <100 times