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Copper(I) π-complexes with allyl derivatives of heterocyclic compounds: structural survey of their crystal engineering

Authors
  • Slyvka, Yurii
  • Goreshnik, Evgeny
  • Pavlyuk, Oleksii
  • Mys’kiv, Marian
Type
Published Article
Journal
Open Chemistry
Publisher
Walter de Gruyter GmbH
Publication Date
Sep 26, 2013
Volume
11
Issue
12
Pages
1875–1901
Identifiers
DOI: 10.2478/s11532-013-0323-3
Source
De Gruyter
Keywords
License
Green

Abstract

In this review an exhaustive crystallochemical analysis of copper(I) π-complexes with allyl derivatives of heterocyclic compounds has been performed. Structural genesis of inorganic constituents starting from the simplest units to the most complicated aggregates was considered taking into account the specific role of Cu-(C=C) interaction, the construction of the organic ligands, the basicity and nucleophilic activity of their heteroatoms, as well as olefin Cu(I) π-complex preparation route.

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