Affordable Access

deepdyve-link deepdyve-link
Publisher Website

Copper-catalyzed direct trifluoromethylthiolation of benzylic C-H bonds via nondirected oxidative C(sp3)-H activation.

Authors
Type
Published Article
Journal
Organic Letters
1523-7052
Publisher
American Chemical Society
Publication Date
Volume
16
Issue
12
Pages
3372–3375
Identifiers
DOI: 10.1021/ol501400u
PMID: 24892973
Source
Medline
License
Unknown

Abstract

A copper-catalyzed trifluoromethylthiolation of benzylic sp(3) C-H bonds was developed via nondirected oxidative C-H activation using readily prepared and stable AgSCF3. This reaction provides a novel and straightforward method for the preparation of various benzyl trifluoromethyl sulfides.

Statistics

Seen <100 times