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Copper-catalyzed direct trifluoromethylthiolation of benzylic C-H bonds via nondirected oxidative C(sp3)-H activation.

Authors
Type
Published Article
Journal
Organic letters
Publication Date
Volume
16
Issue
12
Pages
3372–3375
Identifiers
DOI: 10.1021/ol501400u
PMID: 24892973
Source
Medline

Abstract

A copper-catalyzed trifluoromethylthiolation of benzylic sp(3) C-H bonds was developed via nondirected oxidative C-H activation using readily prepared and stable AgSCF3. This reaction provides a novel and straightforward method for the preparation of various benzyl trifluoromethyl sulfides.

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