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Coordination reaction between tetraphenylporphyrin and nickel on a TiO2(110) surface.

Authors
  • Wang, Cici
  • Fan, Qitang
  • Hu, Shanwei
  • Ju, Huanxin
  • Feng, Xuefei
  • Han, Yong
  • Pan, Haibin
  • Zhu, Junfa
  • Gottfried, J Michael
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Aug 06, 2014
Volume
50
Issue
61
Pages
8291–8294
Identifiers
DOI: 10.1039/c4cc02919d
PMID: 24871136
Source
Medline
License
Unknown

Abstract

In situ metalation of tetraphenylporphyrin (2HTPP) (sub)monolayers with Ni on a TiO2(110) surface to nickel(II)-tetraphenylporphyrin (NiTPP) depends on temperature and order of deposition, and affects conformation and bonding geometry of the porphyrin.

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