Controls and Effects of Monomer Junctions and Sequences in Curable and Degradable Polyarylate Containing Acrylate Moieties.
Research Initiative for Supra-Materials, Shinshu University, 4-17-1 Wakasato, Nagano, Nagano, 380-0928, Japan.
Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, Ueda, Nagano, 386-8567, Japan.
- Published Article
Macromolecular rapid communications
- Publication Date
Dec 02, 2020
In contrast to solution polymerization, interfacial polymerization of α-(chloromethyl)acryloyl chloride and bisphenol Z results in fast esterification and slow ether formation, affording regulated monomer junctions. The controlled structure increases the crystallinity of the resulting polymers. In addition, terpolymerization with dicarboxylic acid chloride results in controlled monomer sequences with uniformly distributed acrylate moieties, leading to efficient curability. © 2020 Wiley‐VCH GmbH.
Report this publication
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.
This record was last updated on 01/04/2021 and may not reflect the most current and accurate biomedical/scientific data available from NLM.
The corresponding record at NLM can be accessed at https://www.ncbi.nlm.nih.gov/pubmed/33289222