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Controls and Effects of Monomer Junctions and Sequences in Curable and Degradable Polyarylate Containing Acrylate Moieties.

Authors
  • Kohsaka, Yasuhiro1, 2
  • Nagai, Koki2
  • 1 Research Initiative for Supra-Materials, Shinshu University, 4-17-1 Wakasato, Nagano, Nagano, 380-0928, Japan. , (Japan)
  • 2 Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, Ueda, Nagano, 386-8567, Japan. , (Japan)
Type
Published Article
Journal
Macromolecular rapid communications
Publication Date
Dec 02, 2020
Identifiers
DOI: 10.1002/marc.202000570
PMID: 33289222
Source
Medline
Keywords
Language
English
License
Unknown

Abstract

In contrast to solution polymerization, interfacial polymerization of α-(chloromethyl)acryloyl chloride and bisphenol Z results in fast esterification and slow ether formation, affording regulated monomer junctions. The controlled structure increases the crystallinity of the resulting polymers. In addition, terpolymerization with dicarboxylic acid chloride results in controlled monomer sequences with uniformly distributed acrylate moieties, leading to efficient curability. © 2020 Wiley‐VCH GmbH.

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