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Compound dependence of the relationship log K(ow) and log BCF L : A comparison between chlorobenzenes (CBs) for rainbow trout and polycyclic aromatic hydrocarbons (PAHs) forDaphnia.

Authors
Type
Published Article
Journal
Environmental Science and Pollution Research
0944-1344
Publisher
Springer Nature
Publication Date
Volume
2
Issue
1
Pages
33–36
Identifiers
DOI: 10.1007/BF02987509
PMID: 24234468
Source
Medline

Abstract

Linear relatinships between log bioconcentration factor (BCF) and log K(ow) for a variety of compounds have been reported many times in the literature. Analysis of the thermodynamics of the two partition processes has, however, shown that they are not analogous and that linear relationships can be expected to have different slopes for structurally unrelated compounds. In this study a set of literature lipid normalized BCF (BCFL) values of chlorbenzenes (CBs) for rainbow trout and polycyclic aromatic hydrocarbons (PAHs) forDaphnia was put together with literature Kow values. The slopes of the regression lines for log BCFL versus log Kow for the two groups of compounds proved to differ significantly in a statistical test using analysis of variance (ANOVA). The difference, which is of significance for estimates of BCFs in environmental modelling of these types of compounds, is explained by the differences in chemical structure of the two groups of compounds.

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