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Component exchange as a synthetically advantageous strategy for the preparation of bicyclic cage compounds.

Authors
  • Alajarín, Mateo1
  • Berná, José
  • López-Leonardo, Carmen
  • Steed, Jonathan W
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
May 28, 2008
Issue
20
Pages
2337–2339
Identifiers
DOI: 10.1039/b801299g
PMID: 18473062
Source
Medline
License
Unknown

Abstract

Macrobicyclic triphosphazides are able to reversibly exchange one of their tripodal components by means of a dynamic disassembly-reassembly process; surprisingly this strategy provides better yields of cage compounds than a direct tripod-tripod coupling.

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