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Chromazurol S ion-selective electrode for chelatometric titration.

Authors
Type
Published Article
Journal
Talanta
0039-9140
Publisher
Elsevier
Publication Date
Volume
24
Issue
4
Pages
261–263
Identifiers
PMID: 18962078
Source
Medline
License
Unknown

Abstract

A liquid membrane type Chromazurol S ion-selective electrode has been constructed and applied to chelatometric titrations. In aqueous medium, zephiramine (benzyldimethyltetradecylammonium chloride) forms with the anion of Chromazurol S an ion-pair which is easily extracted into nitrobenzene. The extract is used as the liquid ion-exchanger for the Chromazurol S ion-selective electrode. The most suitable ion-pair concentration in the liquid ion-exchanger membrane is 10(-4)M. The linear Nernstian-response range of the Chromazurol S anion in aqueous solution is 10(-2)-10(-6)M. The electrode has been successfully applied to the chelatometric titration of Cu(II), Ni(II), Fe(III) and Pb(II) with EDTA.

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