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Chloridometh-yl(2-methyl-quinolin-8-olato-κN,O)phenyl-tin(IV).

Authors
  • Vafaee, Maryam
  • Amini, Mostafa M
  • Ng, Seik Weng
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jul 17, 2010
Volume
66
Issue
Pt 8
Identifiers
DOI: 10.1107/S1600536810027790
PMID: 21588190
Source
Medline
License
Unknown

Abstract

The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol-ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol-ecule with the smaller C-Sn-C angle inter-acts weakly with the Sn(IV) atom of the mol-ecule with the wider C-Sn-C angle at an Sn⋯Cl distance of 3.595 (1) Å. Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonding is present in the crystal structure.

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