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A chiral tetragonal magnesium-carboxylate framework with nanotubular channels.

Authors
  • Lin, Qipu
  • Wu, Tao
  • Zheng, Shou-Tian
  • Bu, Xianhui
  • Feng, Pingyun
Type
Published Article
Journal
Chemical Communications
Publisher
The Royal Society of Chemistry
Publication Date
Nov 21, 2011
Volume
47
Issue
43
Pages
11852–11854
Identifiers
DOI: 10.1039/c1cc14836b
PMID: 21983788
Source
Medline
License
Unknown

Abstract

Reported here is a rare example of a highly symmetrical chiral Mg-based MOF (CPF-1) with nanotubular channels, built from 4(1) (or 4(3)) helical chains. It exhibits a high gas sorption capacity (ca. 1.29 wt% H(2) at 77 K, 1 atm; 84 cm(3) g(-1) of CO(2) at 273 K, 1 atm).

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