Affordable Access

deepdyve-link deepdyve-link
Publisher Website

Chiral cobalt-catalyzed enantioselective aerobic oxidation of α-hydroxy esters.

Authors
Type
Published Article
Journal
Chemical Communications
1364-548X
Publisher
The Royal Society of Chemistry
Publication Date
Volume
46
Issue
38
Pages
7235–7237
Identifiers
DOI: 10.1039/c0cc01917h
PMID: 20820516
Source
Medline
License
Unknown

Abstract

A chiral cobalt-catalyzed enantioselective aerobic oxidative kinetic resolution of (±)-α-hydroxy esters, using molecular oxygen as a sole oxidant, is reported and a maximum of selectivity factor (s) 31.9 was achieved with >99% enantiomeric excess for unreacted α-hydroxy esters.

Statistics

Seen <100 times