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Characterization of porous carbons with high resolution α s-analysis and low temperature magnetic susceptibility

Authors
  • Kaneko, K
  • Ishii, C
  • Kanoh, H
  • Hanzawa, Y
  • Setoyama, N
  • Suzuki, T
Type
Published Article
Journal
Advances in Colloid and Interface Science
Publisher
Elsevier
Publication Date
Jan 01, 1998
Volume
76
Pages
295–320
Identifiers
DOI: 10.1016/S0001-8686(98)00050-5
Source
Elsevier
Keywords
License
Unknown

Abstract

The effectiveness of integrated characterization of porous carbons with different approaches such as the high resolution α s-method for N 2 adsorption, X-ray diffraction, and magnetic susceptibility measurement is shown. The theoretical basis for the high resolution α s-analysis for N 2 adsorption using GCMC simulation and the background of magnetic susceptibility of carbon are given. The applicability of the integrated characterization to changes of ACF with heating at 1473–3173 K in Ar is shown. The activated mesocarbon microbead (a-MCMB) and activated carbon aerogel (a-CA) were examined by the integrated characterization method. a-MCMB showed an unusual magnetic relaxation below 10 K due to random magnetism. The random magnetism was associated with the mutually isolated network structure of nanographitic units. a-CA also showed random magnetism at low temperature, which was associated with the spin isolated nanographitic structure similar to a-MCMB.

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