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Formation of gas-phase lithium complexes from acetogenins and their analysis by fast atom bombardment mass spectrometry

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
33
Issue
36
Identifiers
DOI: 10.1016/s0040-4039(00)79142-8

Abstract

Abstract The Annonaceous acetogenins form complexes with lithium in a liquid matrix. Fast atom bombardment (FAB) combined with linked scan ( B/E and B 2(1 - E)/ E 2) mass spectrometry of a lithium cationized acetogenin, rolliniastatin-2, was used to analyze the metastable dissociations of the complex, leading to structurally useful information.

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