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Transport properties of flash-evaporated (Bi1 − xSbx)2Te3films II: Theoretical analysis

Authors
Journal
Thin Solid Films
0040-6090
Publisher
Elsevier
Publication Date
Volume
187
Issue
2
Identifiers
DOI: 10.1016/0040-6090(90)90048-i
Disciplines
  • Musicology
  • Physics

Abstract

Abstract An analysis of the temperature dependence of several transport properties, particularly the Seebeck and Hall coefficients, of thermoelectrically optimized p-type ( Bi 1 − x Sb x ) 2 Te 3 films is carried out in the interval from 80 to 350 K for x = 0.75 including a comparison with bulk material data. The model calculations are based on the solution of the homogeneous Boltzmann equation in a relaxation time approximation since the films exhibit an in some ways bulk-like behaviour, e.g. the Hall mobility is of the order of that of the bulk material. In the framework of a one-valence-band model, the analysis of both bulk and film data favours a non-parabolic dispersion relation for Bi 0.5Sb 1.5Te 3. It is shown that acoustic intravalley scattering is the predominant scattering mechanism of the charge carriers in the thermoelectrically optimized films.

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