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An ultraviolet photoelectron spectroscopic study of the electron states of iodine complexes with electron donors

Authors
Publisher
Elsevier Science
Publication Date
Keywords
  • Solid State & Structural Chemistry Unit

Abstract

HeI photoelectron spectra of the vapour phase complexes of diethylether and diethylsulphide with iodine have been investigated for the first time. The iodine orbital ionization energy decreases on complexation while the donor lone-pair orbital ionization energy increases markedly; the shifts are considerably larger in the sulphide complex as expected on the basis of enthalpy considerations.

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