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Oxidation of amines and sulfides by 3-bromo-4,5-dihydro-5-hydroperoxy-4,4-dimethyl-3,5-diphenyl-3h-pyrazole

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
22
Issue
46
Identifiers
DOI: 10.1016/s0040-4039(01)82989-0

Abstract

Abstract The reaction of 3-bromo-4,5-dihydro-5-hydroperoxy-4,4-dimethyl-3,5-diphenyl-3H-pyrazole with tertiary amines and sulfides produced amine oxides and sulfoxides in high yield with k 2's for amines similar to those reported for reaction of amines with a 4a-hydroperoxyflavin.

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