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Schwingungsspektren und Kraftkonstanten von Bortrimethyl und Rubidiumtetramethylboranat

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
35
Issue
1
Identifiers
DOI: 10.1016/0584-8539(79)80064-1
Disciplines
  • Physics

Abstract

Abstract A more precise and extended evaluation of H/D- and 11B/ 10B-shifts was obtained from a new Raman and infraredspectroscopic examination of B(CH 3) 3 and B(CD 3) 3. A set of force constants is given including interaction terms which are sensitive to the observed isotopic shifts. The Raman and infrared spectra of MB(CH 3) 4 with M = Na, K, Rb have been examined. Force constants of the B(CH 3) − 4 anion are calculated from its fundamentals using a potential function comparable to that of B(CH 3) 3.

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