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Asymmetric synthesis with diphenylphosphine oxides: Bicyclic aminals and oxazolidines as chiral auxiliaries

Authors
Journal
Tetrahedron Asymmetry
0957-4166
Publisher
Elsevier
Publication Date
Volume
7
Issue
12
Identifiers
DOI: 10.1016/s0957-4166(96)00451-x

Abstract

Abstract Syntheses of six novel phosphine oxide chiral auxiliaries are described. The auxiliaries are composed of the diphenylphosphinoyl (Ph 2PO) group and either proline-derived bicyclic aminals or norephedrine-derived oxazolidines. One auxiliary is used in the synthesis of an optically active β-hydroxy phosphine oxide.

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