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catena-Poly[[tetra-kis(hexa-methyl-phos-pho-ramide-κO)bis-(nitrato-κO,O')neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]].

Authors
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
64
Issue
Pt 3
Identifiers
DOI: 10.1107/S1600536808001256
PMID: 21201866
Source
Medline
License
Unknown

Abstract

In the title compound, {[Nd(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the central Nd atom of the monovalent cation is coordinated by eight O atoms from two nitrate and four hexa-methyl-phospho-ramide ligands. The monovalent anion, {[WS(4)Ag](-)}(n), forms a polymeric chain in a distorted linear configuration with W-Ag-W and Ag-W-Ag angles of 163.81 (3) and 154.786 (12)°, respectively. Thirteen C and three N atoms are disordered equally over two positions. One C atom is disordered over two positions with site occupancy factors of 0.6 and 0.4.

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