Affordable Access

deepdyve-link deepdyve-link
Publisher Website

catena-Poly[di-μ3-bromido-bis-[(1-ethyl-1H-imidazole-κN (3))disilver(I)]].

Authors
  • 1
  • 1 Department of Chemistry and Chemical Engineering, Mianyang Normal University, Mianyang 621000, People's Republic of China. , (China)
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
69
Issue
Pt 7
Identifiers
DOI: 10.1107/S1600536813016875
PMID: 24046580
Source
Medline
License
Unknown

Abstract

The asymmetric unit of the title coordination complex, [Ag2Br2(C5H8N2)2] n , comprises a monodentate 1-ethyl-imida-zole ligand, an Ag(+) cation and a μ3-bridging Br(-) anion, giving a distorted tetra-hedral AgNBr3 stereochemistry about the Ag(+) cation [Ag-N = 2.247 (2) Å and Ag-Br = 2.7372 (4)-2.7523 (4) Å]. Two bridging bromide anions generate the dimeric [Ag2Br2(C5H8N)2] repeat unit [Ag⋯Ag = 3.0028 (5) Å], while a third Br(-) anion links the units through corner sharing in an inversion-related Ag2Br2 association [Ag⋯Ag = 3.0407 (4) Å], generating a one-dimensional ribbon step-polymer structure, extending along the c axis.

Statistics

Seen <100 times