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An isomer effect on the chemisorption of the pentanols on Cab-O-Sil

Authors
Journal
Journal of Colloid and Interface Science
0021-9797
Publisher
Elsevier
Publication Date
Volume
45
Issue
3
Identifiers
DOI: 10.1016/0021-9797(73)90159-8
Disciplines
  • Mathematics

Abstract

Abstract The physisorption and chemisorption of a number of pentanols on Cab-O-Sil activated under vacuum at 55, 400 or 900°C is described. It is shown that both the rate and amount of chemisorption are critically dependent on the molecular geometry of the pentanol. The chemisorption reactivity of the molecules decreased in the order: normal > iso > secondary > neo > tertiary The mechanism of the chemisorption reaction is discussed.

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