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Anionic amido/carbocyclic carbene ligated palladium (II) complex for room temperature Suzuki reaction

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
729
Identifiers
DOI: 10.1016/j.jorganchem.2013.01.013
Keywords
  • Suzuki Reaction
  • Carbocyclic Carbene
  • Phosphine-Free
  • Palladium
  • Room Temperature

Abstract

Graphical abstract The synthesis of anionic amido/carbocyclic carbene ligated Pd (II) complex has been reported. The palladium complex is an active catalyst for the cross-coupling reaction between aryl and phenylboronic acids under phosphine-free conditions at room temperature. Highlights ► Synthesis of multi-functional and multi-donor ligand from amino alcohol. ► Preparation of stable anionic amido/carbocyclic carbene ligated Pd (II) complex. ► Highly efficient catalysts for Suzuki reaction of deactivated aryl bromides and iodides.

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