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Free radical-mediated addition of peracetylated 1-bromo-β-d-glucopyranosyl chloride to acrylonitrile

Authors
Journal
Carbohydrate Research
0008-6215
Publisher
Elsevier
Publication Date
Volume
232
Issue
1
Identifiers
DOI: 10.1016/s0008-6215(00)90998-4

Abstract

Abstract Dropwise addition of a benzene solution of tri- n-butylstannane to a solution of 2,3,4,6-tetra- O-acetyl-1-bromo-β- d-glucopyranosyl chloride in boiling benzene containing acrylonitrile in excess led predominantly, under photolytic conditions, to a mixture of nonononitriles, either chlorinated or unsaturated.

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