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Photoelectron spectra and molecular properties XV. The effects of α and β-silyl substituents on π-systems

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
46
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)90477-7

Abstract

Abstract The photoelectron spectra of substituted ethylenes , H 2C=CHX (X = H, CH 3, SiH 3, CH 2CH 3, CH 2SiH 3) are discussed in the light of the results of CNDO-type molecular orbital calculations. The characteristic shifts of the first bands are explained in terms of a qualitative model for the substituent effect of α- and β-silyl group upon π-systems.

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