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An intramolecular rhodium carbenoid C-H insertion approach to chiral isotwistanes. Synthesis of (-)-neopupukean-4,10-dione and (-)-neopupukean-10-one

Authors
Publisher
Royal Society of Chemistry
Publication Date
Keywords
  • Organic Chemistry

Abstract

The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Michael reaction and a regioselective intramolecular rhodium carbenoid C-H insertion reaction as key steps, is described.

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