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A dialkylborenium ion via reaction of N-heterocyclic carbene-organoboranes with Brønsted acids - synthesis and DOSY NMR studies

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Abstract

A dialkylborenium ion stabilized by an N-heterocyclic carbene has been prepared for the first time by reaction of IMes·9-BBN-H with triflic acid. The ion-separated nature of the borenium ion was confirmed by 1H and 19F diffusion ordered NMR spectroscopy.

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