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EPR studies of spin-crossover of the tris-(di-n-butyldithiocarbamato)Fe(III) chlorobenzene solvate

Authors
Journal
Journal of Inorganic and Nuclear Chemistry
0022-1902
Publisher
Elsevier
Publication Date
Volume
42
Issue
8
Identifiers
DOI: 10.1016/0022-1902(80)80424-6

Abstract

Abstract EPR studies of tris-(di- n-butyldithiocarbamato)Fe(III), with and without a chlorobenzene solvate, were performed from −160°C to room temperature. A line at an approximate g-value of 4.4 was assigned as a S = 5 2 line and its temperature dependent behavior was correlated with solid magnetic moment observations. An additional narrower line was noted in the spectrum of the solvated sample. We associate this line with a second possible high-energy site for the chlorobenzene solvate molecule. A solvate molecule in this site appears to “shut off” the spin-crossover.

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