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Comparative nucleophilic reactivities in phosphodiester cleavage

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
43
Issue
23
Identifiers
DOI: 10.1016/s0040-4039(02)00777-3

Abstract

Abstract o-Iodosobenzoate ( 2 ) and 2,3-iodosonaphthoate ( 4 ) cleave phosphodiester substrate 3 in cationic micelles at pH 9 with rate accelerations of 1200 or 5800, respectively.

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