Affordable Access

Publisher Website

Factors affecting stereochemical control in directed homogeneous hydrogenation of α-hydroxyalkylacrylates

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
27
Issue
28
Identifiers
DOI: 10.1016/s0040-4039(00)84783-8

Abstract

Abstract The degree of asymmetric induction observed in hydrogenation of menthyl 3-hydroxy-2-methylenebutyrates catalysed by DIPAMP-Rh + complexes is strongly dependent on the configuration of the menthyl group. For a related methyl ester syn as well as anti -reduction product is formed with high enantioselection.

There are no comments yet on this publication. Be the first to share your thoughts.