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Intramolecular Horner-Wadsworth-Emmons reaction in base sensitive substrates: Enantiospecific synthesis of iridoid monoterpene lactones

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
35
Issue
22
Identifiers
DOI: 10.1016/s0040-4039(00)73091-7

Abstract

Abstract The cyclopentapyranones (-)- 7 and (-)- 13, representing the cis -fused 9-carbon core of iridoid lactones, are synthesised from (+)-pulegone.

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